So I simmered enhanced leaf made from freebase and damiana in water and fb dissolved perfectly. Wondering what conversion took place ?

DMT damianate

In reality it can be any possible salt from the acids normally found in damiana, most likely a combination of many different salts reflecting the many different acids normally found in plants.

I find it hard to believe that there were enough salts from damiana to convert all dmt. can you describe your procedure accurately?

I see. Nothing fancy really, just dropped a bunch of leaf into near simmering water and left it for an hour. Then reduced further. Water has a strong dmt taste and strained leaf is tasteless hence I considered it dissolved.

Dmt:leaf ratio was only .4-.5 to 1 though, which is perhaps the reason it was enough