If you add vinegar to your basic solution the DMT will be in salt form and will be insoluble in naphtha. After this you will need to re-basify the solution but I can't see why you would want to do that in your situation.
It has been posited that adding excess salt to the basic solution will help DMT to be more readily dissolved in naptha, I have only tried this a couple of times and saw no real difference from my normal extractions, but I didn't do side-by-side tests.
Maybe you could add salt to your basic solution to see if this will help you grab a bit more from it. Give it a go, not much to lose except time.