The longer you let the naphtha sit, the more spice it will pull. However, if the naphtha is fully saturated with spice, then it will not hold any more. But 24 hours is MUCH better than just 1 hour. Some let it sit for days (but not always recommended).
Warming naphtha I dont know too much about. I thought it was for the last pull or two, but some say always heat it. I will let others chime on this one if they want.
Cheers!
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