I think I’ve figured out the DMT boiling point conundrum: The reason that boiling points for DMT are always shown at reduced pressure is because DMT decomposes at temperatures below that of its extrapolated standard atmospheric pressure boiling point.
My guess is that DMT decomposes at a temperature below 382ºC. This is why you’ll never see a BP listed at that temperature. This value can be extrapolated from reduced pressure BPs, but it’s a “theoretical” BP, and not an actual BP.
A simple organic molecule that behaves similarly is sucrose. It melts, but never boils. It decomposes (caramelizes, then eventually carbonizes) before it ever reaches its boiling point.
So the vapors from DMT are not produced by boiling, but by evaporation at a temperature below the BP and ideally below the temperature at which DMT begins to decompose.
Does any of this make sense?
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