Thanks Pandora and Orion for the warm welcome, the days of dark forums where strangers collect to discuss the occult is not dead it seems. Rejoice!
Planning to do another 300g extraction of the acuminata soon, and would like to document the process thoroughly and post here. In the first run I roughly followed a guide on r/dmtguide that specified use of acuminata, in the base step it had me adding 125g of NaCl, and 150g of NaOH, in solutions which totalled 2L when added to the reduced vinegar/water pulls on 500g of bark. Scaled all this for 300g. After extracting with Shellite (Naptha) and first crystallization I had 6g(!) of white crystal crown clusters that had a distinct NaOH/DMT aroma.
Dissolved in hexane, and after washing with NaCO3 solution and distilled water, and after spilling perhaps 1/6th out of the sep funnel (curses) the recrystallisation was 3g, half the amount.
Now I'm not complaining as I am certain this is some seriously pure DMT, however I think the original Tek uses too much NaOH or the NaCl is crashing out or is pushing NaOH out, or NaCl and/or NaOH do not scale linearly, as it was definetly quite contaminated after the first run, fooling me into thinking I had achieved 100% theoretically yield 1st try (the arrogance!). Also some DMT might have gone into the aqueous layers when washing.
Having now run the Tao of Rue a few times I feel much better equipped to understand the basing step. I will add NaOH by eye and by PH reading next time. What are thoughts on adding NaCl?
The other mystery that alludes me for now is seperating harmine/harmaline. After many manske, the final HCl mix crystallised out of clear yellow solution, and was a golden yellow/light orange. An amount in mild acetic solution was based with NaCl to 8.75 filtered, and further based to 12, the latter filtrate yielded a measly 120mg, that had the same light tan appearance (not yellow) and also glowed aqua to UV in acidic solution. Is it possible the seeds didn't contain much if any harmaline or have I been discarding it accidentally along the way? Or some other explanation. I will try extraction on a different source in the future but for now I'm considering proceeding with THH conversion on some earlier 'unseperated' product input aside, as seen in GordoTEKs video.
As well as this forum I've been learning from some great books, tihkal/pihkal, organic chem lab survival, food of the gods, moksha, the nature of drugs, and lucky to have a friend who's been interested in this subject for a couple of decades with mamy more reads lined up, any recommendations?
I enjoy the feeling of awakening of an inner alchemist that this all brings about, almost as much as the experiences them selves. It's part and parcel and it feels right, much different to the shady whispers of deals and unknown pills and powers.
Having already invested a bit in materials and tools for extraction, will try some low cost cupboard teks, but also inspired by a video by North Spore (YouTube) in which he demonstrated wild farming mycelium outdoors. Will attempt this type of thing with subaeruginosa as the season is near and a friend has alluded to knowing some absolutely abundant locations! Love the idea of being a mushroom elf going around and spreading the mycelium. Any thoughts on this?
I'm guessing there are better places to put these reports and questions but consider it an appendix to the essay.