I love mushrooms but they are fungi not plants. My favourites are cannabis and salvia, currently, because i can cultivate them at home, working on cultivating some cacti, so a few more names might join my list soon! My dreams are to someday have an entire psychoactive garden  psychedelia inc.
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Psychoactive, but not psychedelic: Albizia Julibrissin
I started growing one from seed last year.
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Nice, might add one to the collection, i want to start growing Kratom as well psychedelia inc.
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Mary Jane and I have had something special going on...  She's also fun to grow, but i think my favorite so far have to be either trichocereus cacti or tobacco. ॐ असतो मा सद्गमय ।
तमसो मा ज्योतिर्गमय ।
मृत्योर्मा अमृतं गमय ।
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Californian poppies, Eschscholzia californica are very lovely, and a great, non-habituating, anxiolytic medication. Trichocereus cacti are, of course, rather splendid as well  And at the moment my Ipomoeas are flowering, also very lovely. “There is a way of manipulating matter and energy so as to produce what modern scientists call 'a field of force'. The field acts on the observer and puts him in a privileged position vis-à-vis the universe. From this position he has access to the realities which are ordinarily hidden from us by time and space, matter and energy. This is what we call the Great Work." ― Jacques Bergier, quoting Fulcanelli
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