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solvent for Caapi 10x ? Options
 
EmptyHand
#1 Posted : 10/6/2011 8:48:23 PM

What would be a better solvent, 91% Isopropyl Alchohol or 151 proof Everclear for the following Caapi 10x prep? Why? (190 proof Everclear is not available in my state.)

https://www.dmt-nexus.me...aspx?g=posts&t=12527


eH
 
damon
#2 Posted : 10/6/2011 8:57:14 PM
I would choose the 91% IPA because it's much cheaper and will dry faster. The smell also dissipates faster and will draw less attention. Other than that, the two will work equally well.
 
Infundibulum
ModeratorChemical expert
#3 Posted : 10/6/2011 9:12:26 PM
Both everclear and IPA really suck when it comes to harmala extraction. The best and most available solvent for 10x caapi is water. It doesn't evaporate as fast, but is sure pulls far more alks than the alcohols.

That is not to say that IPA or everclear will not work, but multiple soaks are necessary to exhaust the material and make a "true" 10x caapi.


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dreamer042
Moderator | Skills: Mostly harmless
#4 Posted : 10/6/2011 9:18:47 PM
I was under the impression vodka was a good candidate for this, since its got a nice ratio of water to ethanol you get the best of both worlds and a gallon of rotgut is super cheap!

I had great success using 95% everclear don't know if I got everything there was to get but it's darn effective.
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Infundibulum
ModeratorChemical expert
#5 Posted : 10/6/2011 9:37:12 PM
dreamer042 wrote:
I was under the impression vodka was a good candidate for this, since its got a nice ratio of water to ethanol you get the best of both worlds and a gallon of rotgut is super cheap!

Maybe, but what is the advantage of ethanol over water when it comes to caapi? what part in the magic of gets better extracted with ethanol over water?

dreamer042 wrote:
I had great success using 95% everclear don't know if I got everything there was to get but it's darn effective.

Oh, people definitely have success with both IPA and everclear. It all depends on how you use your solvent. For ethanol and IPA I'd soak and filter caapi at least 5-10 times before I evaporate it onto fresh caapi so as to call it a "true" 10x. With water I'd boil 3-4 times and then evaporate it on fresh caapi to the same effect.



Need to calculate between salts and freebases? Click here!
Need to calculate freebase or salt percentage at a given pH? Click here!

 
endlessness
#6 Posted : 10/6/2011 10:13:05 PM
Please dont use IPA for harmalas, it sucks big time! Just try it out yourself, with pure alkaloids. Even freebase (which are generally much more soluble in alcohols than salts) are poorly soluble in IPA, so the natural salt form in caapi must be only slightly soluble in it. Sure you might get some psychoactive product, but dont throw that caapi away, extract it with water afterwards and you'll most likely get a significant amount of alkaloids. Ethanol is better than IPA for this, but I would still go for water
 
joedirt
Senior Member
#7 Posted : 10/6/2011 10:17:32 PM
endlessness wrote:
Please dont use IPA for harmalas, it sucks big time! Just try it out yourself, with pure alkaloids. Even freebase (which are generally much more soluble in alcohols than salts) are poorly soluble in IPA, so the natural salt form in caapi must be only slightly soluble in it. Sure you might get some psychoactive product, but dont throw that caapi away, extract it with water afterwards and you'll most likely get a significant amount of alkaloids. Ethanol is better than IPA for this, but I would still go for water


I agree with this, but I want to add that once you have crystalized free base product it is usually a good bit harder to get it back into solution.

However, he is not freebasing them....he is just collecting the salt based alkaloids which should be pretty soluble in either IPA or ethanol IMHO.

What I find interesting is that it does appear that you can smoke harmalas in the natural salt form as caapi leaf is slightly active.
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Ice House
#8 Posted : 10/8/2011 4:56:53 AM
Infundibulum wrote:
Both everclear and IPA really suck when it comes to harmala extraction. The best and most available solvent for 10x caapi is water. It doesn't evaporate as fast, but is sure pulls far more alks than the alcohols.

That is not to say that IPA or everclear will not work, but multiple soaks are necessary to exhaust the material and make a "true" 10x caapi.



endlessness wrote:
Please dont use IPA for harmalas, it sucks big time! Just try it out yourself, with pure alkaloids. Even freebase (which are generally much more soluble in alcohols than salts) are poorly soluble in IPA, so the natural salt form in caapi must be only slightly soluble in it. Sure you might get some psychoactive product, but dont throw that caapi away, extract it with water afterwards and you'll most likely get a significant amount of alkaloids. Ethanol is better than IPA for this, but I would still go for water


Okay so are you also referring to making 10x caapi for use in changa? I have always used 99% IPA and allowed for a solid month long soak, shaking the jar every other day minimum. By the end of the month there is a noticeable breakdown in the caapi leaf I am using. I always assumed using this method I was getting the best possible menstrum I could get to use to soak my caaipi leaf in. Are you two saying I could do better by doing this with water, doing several boils, collect em all together, reduce and the use that for my changa?
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endlessness
#9 Posted : 10/8/2011 8:16:45 AM
I would say extract the alkaloids by later basing the acidic soup, like gibran's tek or harmala extraction guide (without the manske part), and add that to the changa in whatever amount you want. Or at the very least try to do this on the supposedly 'spent' caapi after your "10x" soak, and see if you can get more alkaloids out.
 
EmptyHand
#10 Posted : 10/8/2011 9:53:42 AM

Let me rephrase my question a little bit. The goal is to make 10x Caapi leaf for use in changa. Consider the following two techniques. Which works better for making the menstrum?

1. 3 week soak in 91% IPA, shaking daily (Dorge's original technique)

2. Repeat 3 times 10 hour overnight simmers in crockpot on high in water, collect water, reduce.

Thanks!


eH
 
dreamer042
Moderator | Skills: Mostly harmless
#11 Posted : 10/8/2011 9:18:31 PM
I was thinking about this and how about using distilled vinegar as the solvent, being acidified water it should pull all the alks and upon evaporation and heating even freebase them, like in the blab jazz technique?

Just something that came to mind. What do you guys think?
Row, row, row your boat, Gently down the stream. Merrily, merrily, merrily, merrily...

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Visual diagram for the administration of ayahuasca
 
 
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